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Propargyl Alcohol | High Purity, Reliable Supply
Oct . 25, 2025 15:20 Back to list

Propargyl Alcohol | High Purity, Reliable Supply


Propargyl alcohol: the small molecule that punches above its weight

In specialty chemicals, a few grams can change a process. That’s why Propargyl Alcohol keeps cropping up in conversations with formulators and plant engineers. To be honest, it’s a modest-looking liquid—yet in corrosion control packages and as a reactive intermediate, it regularly outperforms its category.

What it is and why it matters

Propargyl Alcohol (CAS 107-19-7) is an acetylenic alcohol with two “reactive sides”: the terminal alkyne and the hydroxyl. That duality is why it’s popular in synthesis (pharma, agro, fine chems) and as a corrosion inhibitor component in industrial and professional systems—cooling-water blends, oilfield packages, metalworking fluids. Many customers say it “does a lot with a little,” which, in my experience, is accurate when purity and water are tightly controlled.

Industry trend snapshot

  • Shift to multi-functional additives: Propargyl Alcohol provides film reinforcement and cathodic suppression in low-dose programs.
  • Cleaner synthesis routes: demand for high-assay, low-water, peroxide-controlled lots for reproducible catalysis.
  • Compliance-first procurement: REACH, ISO 9001/14001, and transparent impurity profiles are now table stakes.

Product specifications (typical)

Chemical namePropargyl Alcohol
Formula / MWC3H4O / 56.06 g·mol−1
Assay (GC)≥ 99.0% (typical 99.5%)
Water (KF)≤ 0.20%
Boiling point≈114–116 °C
Density (20 °C)≈0.97 g/mL
Flash point (CC)≈36 °C
AppearanceClear, colorless liquid
StabilizationPeroxide control; MEHQ ≈100 ppm available on request
Propargyl Alcohol | High Purity, Reliable Supply

How it’s made (process flow, simplified)

Materials: acetylene, formaldehyde solution; copper-based catalyst. Method: Reppe-type addition of acetylene to formaldehyde under controlled temperature/pressure, forming a propargyl/allyl alcohol mixture; followed by phase separation, fractional distillation, polishing (peroxide management), and final QC. Testing: GC assay/impurities (ISO/IEC 17025), water by Karl Fischer (ASTM E1064), density (ASTM D4052), flash point (ASTM D93), color APHA (ASTM D1209). Shelf life: ≈24 months in closed drums, nitrogen-blanketed, 5–30 °C, away from ignition sources.

Applications and advantages

  • Corrosion inhibitor component: improves film persistence in brines and hard waters; lab coupons often show 30–50% lower mass loss vs. base blends (real-world use may vary).
  • Synthesis intermediate: click/alkyne chemistry, propargylated APIs and agro actives, plating bath modifiers, specialty surfactants.
  • Process flexibility: the terminal alkyne enables selective additions; the OH offers straightforward derivatization.

Real-world mini case

A North Asia cooling-tower operator swapped 0.5% of their package for Propargyl Alcohol. Their ASTM G31 loop test showed ≈41% less carbon steel weight loss at 35 °C within four weeks. Operators reported “cleaner start-up” and fewer pH adjustments. Not magic—just tighter control of film formation and oxygen undercutting.

Vendor comparison (indicative)

Vendor Assay Water Packaging Certs Lead time
DFChem (Shijiazhuang, China) ≥99.0% ≤0.20% 190 kg drums; 20 kg cans ISO 9001/14001, REACH-ready 2–4 weeks
EU Supplier A ≥98.5% ≤0.30% IBC; drums ISO 9001 Stock/Just-in-time
US Supplier B ≥99.0% ≤0.25% Drums ISO 9001, NSF non-food claims 3–6 weeks

Customization and QA

Custom specs available: ultra-low water (≤0.05%), tailored inhibitor level, peroxide spec, and drum nitrogen blanketing. Testing against ASTM D4052/D93/E1064 and GC methods; CoAs and SDS supplied. Origin: Room 511, Zelong Building, No.195 Guanghua Road, Shijiazhuang, China 050000.

Safety and handling (quick notes)

  • Flammable liquid; handle per GHS/OSHA guidance; avoid ignition sources.
  • Use peroxide inhibitors as specified; monitor storage stability.
  • PPE: gloves, goggles; local exhaust in synthesis bays.

Customer feedback includes statements like “consistent GC profile” and “less downtime on metering pumps.” It seems the small operational wins add up.

References

  1. PubChem, Propargyl alcohol (CID 10427).
  2. ECHA, 2-propyn-1-ol REACH registration dossier.
  3. NIOSH Pocket Guide to Chemical Hazards: Propargyl alcohol.
  4. ASTM D4052: Density of liquids by oscillating U-tube.
  5. ASTM G31: Laboratory corrosion testing of metals by immersion.

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